To create a new appointment you need to be on the project / company page for which you are planning.
To search for a project follow Step 1 of tutorial How to: Update project / opportunity’s milestone and click on Project link to open project.
Click on Activities link from Quick Navigation Link.

Qucik navigation links for Summary, Value, Milestones, Activities, Statement and Files.
You will be taken to activities section which looks as shown below
Activities section header
Click on “Add Appointment” to get following screen

Add Appointment form
Fill Date, Time, Call Type (Call Type is customizable, contact support@on2.biz), Attendees(Internal), Attendees(External) and Agenda of the appointment. Appointment creation allows you to send agenda to attendees by email.
Click on
to add this appointment.
Once you add appointment you get a email alert on the day of appointment and SMS alert if you have opted for SMS alerts (Contact support@on2.biz for SMS alerts). Also you will be able to see Appointment in Activity list in On2Biz.

Activity List of On2Biz
In activity list you will see your appointment in Scheduled Appointments.
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